Effect of Thickness on Oxidation of Titanium at the Ti/Co3O4 Interface

Document Type

Thesis

Degree Name

Master of Science (MS)

Department

Physics and Astronomy

Date of Award

Summer 8-18-2025

Abstract

Using the X-ray Photoelectron Spectroscopy (XPS), Ti/Co3O4 interface was inves tigated. Cobalt was oxidized ex-situ and a thin layer of Titanium deposited by Physical Vapor Deposition (PVD) on the Co3O4 substrate. The Ti/Co3O4 sample was annealed for several thickness of Titanium with varied annealing Temperatures. The interface of Ti/Co3O4 was characterized by XPS. Titanium gets oxidized into titanium TiO2and other suboxides), whilst Co3O4 gets reduced to CoO and elemental Cobalt. This study probed deeper into the threshold thickness for Ti beyond which it gets no more oxidized while closely examining the temperature effect of physical and chemical change at the interface. We will also look into details the effect of annealing and Titanium thickness on the Physi cal and structural changes at the interface

Advisor

Anil Chourasia

Subject Categories

Physical Sciences and Mathematics | Physics

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